Cho phản ứng \(H{g_2}C{l_2} + 2e = 2Hg + 2C{l^ - }\) . Phương trình Nernst của điện cực calomel là:
A. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{{{\rm{[Hg]}}}^2}.{{{\rm{[}}C{l^ - }{\rm{]}}}^2}}}{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}\)
B. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}{{{{{\rm{[Hg]}}}^2}.{{{\rm{[}}C{l^ - }{\rm{]}}}^2}}}\)
C. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[Hg]}}.{\rm{[}}C{l^ - }{\rm{]}}}}{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}\)
D. \({\varepsilon _{cal}} = 0 + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}{{{\rm{[Hg]}}.{\rm{[}}C{l^ - }{\rm{]}}}}\)
A. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{{{\rm{[Hg]}}}^2}.{{{\rm{[}}C{l^ - }{\rm{]}}}^2}}}{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}\)
B. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}{{{{{\rm{[Hg]}}}^2}.{{{\rm{[}}C{l^ - }{\rm{]}}}^2}}}\)
C. \({\varepsilon _{cal}} = {\varepsilon ^o}_{cal} + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[Hg]}}.{\rm{[}}C{l^ - }{\rm{]}}}}{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}\)
D. \({\varepsilon _{cal}} = 0 + \frac{{RT}}{{2F}}\lg \frac{{{\rm{[}}H{g_2}C{l_2}{\rm{]}}}}{{{\rm{[Hg]}}.{\rm{[}}C{l^ - }{\rm{]}}}}\)